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Intro= duction to the fumigant
Dimet= hyl Disulfide (DMDS)
(a methyl-bromide replacement candidate)
Under development by Cerexagi, Inc., and Arkema, Inc.
Roy Whitson
Field Development Representative
Fresn= o, CA
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=
Current Important
Industrial Use= s of DMDS
•
•Important agent used in hydrodesulfurisation processes in the petrochemical industry
•= 3;
•Coke inhibiting agent used in ethyl= ene furnaces
»
•Used as an FDA approved food additi= ve <= span style=3D'font-size:88%;color:maroon;mso-color-index:5'>
•Arkema, Inc. is the leading produce= r of DMDS in the world
Dick’s Notes:  Arkema is one of= the leading world-wide producer and distributor of DMDS.

Added to catalysts like Mo oxide to transform to Mo sulfide, increasing activity of catalysts used for removing sulfur compounds from petrochemical stream
Used in high volumes throughout the world with acceptable regulatory assessment
Used in food industry with acceptable regulatory assessment
   DMDS is efficacious for so= il treatment of nematodes, fungi, and plants



Natural compound created in abundance in oceans and on land

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Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
DMDS physico-chemical properties
•Molecular formula: C2S2H6   or   CH3-S-S-CH3
•Molecular weight: 94.201
•Appearance: yellow liquid
•Odor: strong garlic-like/petroleum smell
•Boiling point: 109.8° C
•Flash point: 16° C (TCC)
•Henry’s law constan= t: 1.21 E-3 (20° C)
•Octanol/water partition: = log Pow 1.77
•Vapor pressure: 28.7 mm Hg (25° C)
•Water solubility: 3 g/L (25° C)
Sulfur smell is being addressed by the addition of an odorant that is currently = in the process of being Panel tested in the laboratory and evaluated in field tests.
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Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
DMDS Atmospheric Effects
•Half-life in the upper atmosphere predicted to be = = on the order of several hours&= #13;
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•Part of the natural atmospheric sulfur cycle with = formation of acidic sulfur products
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•Ozone depleting potential (ODP) is 0
Chemical mechanisms have been defined that actually provide for the potential to increase ozone formation in upper atmosphere
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Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
Acute oral LD50 (rat): 150 – 240 mg/kg
Acute Inhalation LC50 (rat): 5079 mg/m3 
Acute dermal LD50 (rabbit): >2000 mg/kg=
Dermal irritation: irritant (Tox. Category III) =
Eye irritation: irritant (Tox. Category III)
Dermal sensitivity: non-sensitizer
Genotoxicity: negative
Chronic effects: studies under development <= /span>
DMDS preliminary toxicological profile= 3;
Because of the strong odor associated with DMDS and by-products, special considerations need to be considered in designing studies, especially long-term studies.  In reali= ty, these odor issues will be compensated by the use of an odorant additive.<= /font>
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Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
=
•
•Living Organisms
•Salt Water
•Brackish Water
•Fresh Water =
•Sediment
•Soil
•Atmosphere
= 3;
DMDS
N= aturally Occurring
i= n the Environment
Dick’s Notes:  Ubiquitous
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------=_NextPart_01C5C2C5.ECD75CD0 Content-Location: file:///C:/A2133CD3/OptimizedWhitson_DMDS_files/slide0018.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
DMDS Residues in the Environment: = Biological Sources
• in Procaryotes
–bacteria (Pseudomo= nas fluorescens, Proteus vulgaris, Sarcina lutea)
–fungi (Rhizopus nigricans, Aspergillus oryzae, Fusarium culmorum)
–algae (blue-green, green)
–<= /span>
• in Plants= 3;
–crops (alfalfa, brussels sprouts, cabbage, cassava, cauliflower, cocoa, filbe= rts, garlic, onion, pea, peanut, potato, rutabaga, tea, tomato)
–aquatic plants
–terrestrial plants (oak, pine) =
»
• in Animals&#= 13;
–humans (expired air, urine), cattle (milk, manure),
– poultry/ sheep/ swine (manure), shellfish (oyster meat)
Emphasize the fact that we expel DMDS (albeit at low concentrations) when we breath= e
------=_NextPart_01C5C2C5.ECD75CD0 Content-Location: file:///C:/A2133CD3/OptimizedWhitson_DMDS_files/slide0019.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
DMDS Residues in the Environment:
•
• in Food Proc= essed Commodities
–<= /span>coffee, bread, fish processing, whiskey, beer, wat= er treatment
–= 3;
• in Substance= s from Industrial Processes
–<= /span>previously described industrial uses, sulfur dioxi= de scrubbing, wood pulping, gas= oline engine exhaust, food refuse, starch manufacturing, pesticides1 
–  
–        = ;            &n= bsp;    1/ terminal residues of acephate and methamidophos
------=_NextPart_01C5C2C5.ECD75CD0 Content-Location: file:///C:/A2133CD3/OptimizedWhitson_DMDS_files/slide0015.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" DMDS California
DMDS
Natu= rally Ammended into Soil
Concentrations =
of
volatile =
S
-
containing
compounds
in =
headspace
of
sandy
-
loam
amended
with
Brassica
juncea
leaf
tissue =
(18)
days
0
100
200
300
400
2
4
6
8
10
12
DMDS
Dimethyl
sulfide
Carbon
disulfide
Concentration in
nmole
/g
Concentrations =
of
volatile =
S
-
containing
compounds
in =
headspace
of
sandy
-
loam
amended
with
Brassica
juncea
leaf
tissue =
(18)
days
0
100
200
300
400
2
4
6
8
10
12
DMDS
Dimethyl
sulfide
Carbon
disulfide
Concentration in
nmole
/g
days
0
100
200
300
400
2
4
6
8
10
12
DMDS
Dimethyl
sulfide
Carbon
disulfide
Concentration in
nmole
/g
Already cases, though unknowingly of using DMDS and other sulfurous compounds as a fumigant, though at much lower than optimum therapeutic doses  Brassica Juncea =3D mustard gree= ns, Indian Mustard or Brown Mustard
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