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Vapam®/K-Pam®  
Soil Fumigant
February 11, 2005
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Vapam®/K-Pam® Soil Fumiga= nt
• Previous research and evaluations were  focused on the following:
•<= /span>Suppress nematodes
•<= /span>Manage diseases
•<= /span>Reduce weed seed reservoir
•<= /span>Reduce the length of crop rotation needed by Understanding economical levels =
•<= /span>Metam as a methyl bromide replacement was not an earlier research focus
•
Historical Perspective
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   CH3 - N =3D C =3D S     +   NaSH
C= H3-N- C- S Na
H   S=
Methyl Isothiocyanate
 (MITC)
Metam
Sodium Hydrosulfide
CONVERSION OF METAM IN = SOIL = ;
Vapam®/K-Pam® Soil Fumigant
•Liquid
•Moves in Soil Water
•Low Biological Activity
•Gas
•Moves in soil air/water
•Primary Biological Activity
Conversion Rate Depends on Soil and Environmental Factors
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   CH3 - N =3D C =3D S     +   NaSH
C= H3-N- C- S Na
H   S=
Methyl Isothiocyanate
 (MITC)
Metam
Potassium <= span style=3D'position:absolute;top:55.75%;left:66.1%;width:18.16%;height:2.75%= '>Hydrosulfide
CONVERSION OF METAM IN = SOIL = ;
Vapam®/K-Pam® Soil Fumigant
•<= /span>Liquid
•Moves in S= oil Water
•Low Biolog= ical Activity
•<= /span>Gas
•<= /span>Moves in soil air/water
•<= /span>Primary Biological Activity
Conversion Rate Depends on Soil and Environmental Factors
c
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Breakdown of Metam in Soil
<= span style=3D'font-family:Arial;font-size:83%'>MITC (Methyl = Isothiocyanate)
H20
(Water)
= +
Plant nutrient
Soil = carbon
7 – 14 DAYS
Application
Bio-incorporation
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Vapam®/K-Pam® Soil Fumiga= nt Metabolite Comparison
•<= span style=3D'font-size:86%'>K-Pam HL @ 30 gal/A (equivalent to 37.5 gal/A of Vapam HL)
<= span style=3D'font-size:86%'>•Sulfur  =3D  76#/A =
<= span style=3D'font-size:86%'>•Nitrogen =3D  17#/A
•Potassium as K2O =3D  56#/A
<= span style=3D'visibility:hidden'>•
<= span style=3D'visibility:hidden'>•
<= span style=3D'visibility:hidden'>•
•= Vapam HL @ 37.5 gal/A
•
<= span style=3D'font-size:86%'>•Sulfur =3D 79#/A
<= span style=3D'font-size:86%'>•Nitrogen =3D 17#/A
<= span style=3D'font-size:121%;visibility:hidden'>•
•
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 Vapam®/K-Pam® Soil Fumiga= nt
•Pests Controlled
•
•<= /span>Nematodes (most susceptible, but most difficult= to reach)
•
•<= /span>Diseases (medium susceptibility, located differentially throughout soil profile and can = be difficult to reach)
•
•<= /span>Weeds (most difficult to control, easy location= )
–
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Applic= ation Flexibility
•<= /span>Chemigation:
–- Center Pivot&#= 13;
–- Solid Set Sprinkler
–- Traveling Gun&= #13;
–- Drip Irrigatio= n
•<= /span>Applications mechanically in the soil <= /span>
• - Shank injection – spacing and depth?
–- Power Tiller&#= 13;
–- Spray blade= 3;
•Vapam/K-Pa= m as a base treatment
• - Combination with chloropicrin
–- Combination with  1,3-D
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Tarp      Seal
No Seal
Soil Seal
10~12”
Methyl Bromide Movement
Injection Shank
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MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
   No    Seal
No Seal
No Seal
Vapam= /K-Pam Movement
 
 
 
 
 
 
 
 
 
 
Dry soil
Dry soil
Injection Shank
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Water     &nb= sp; Seal
Soil      Seal
Tarp     Se= al
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
MITC
Vapam= /K-Pam Movement
Soil        Seal
Injection Shank
Injection Shank
Injection Shank
<= ![if !ppt]>
Pre-moisture
Pre-moisture
3~4”
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•<= /span>Prepare the soil to to facilitate water movement in the soil profile to be treated.
•<= /span>Thoroughly chop or work in excessive surface = crop residue.
•<= /span>Soil surface must be free of large clods or piles of crop residue.
•<= /span>Pre-irrigate a minimum of 7- 10 days prior to Vapam application and ensure soil moisture = = of 50-80%.
•<= /span>
APPLICATION  GUIDELINES
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<= span style=3D'visibility:hidden'>•
<= span style=3D'font-size:88%'>•Check the soil temperature at 6 inches =
•Know what the soil moisture is before and  at <= span style=3D'font-size:88%'>application
<= span style=3D'font-size:88%'>•Use the properly labeled rate
<= span style=3D'font-size:88%'>•Check the calibration during application
<= span style=3D'font-size:88%'>•Application system should be leak free =
•
•
APPLICATION  GUIDELINES
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<= span style=3D'font-size:88%;visibility:hidden'>•
•A lethal concentration of Vapam must be present = while the target species is actively respiring.= 3;
<= span style=3D'font-size:88%'>•Avoid skips in the treatment zone
•Immediately following application, the soil must b= e = sealed (water, soil, tarp) •Reinfestation of the treated zone must be avoided = <= span style=3D'font-size:88%'>after the application.
•
•
APPLICATION  GUIDELINES
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•Odor Mitigation Requirements: Soil sealing methods include, but are not limited to, the following:= 3;
•<= /span>
•<= /span>Water sealing– In general 1/4 inch of water = or two-hour sprinkler se= t may be adequate for sandy or light soil, less water or shorter set for heavier soil
•<= /span>Soil capping—Placing on the treated soil 3-6 inches of untreated soil&= #13;
•Compacting the treated soil – Using a bed sh= aper, roller, press wheel, or similar device =
•
•Consult the label and the Technic= al Information Bulletin before any application
•
APPLICATION GUIDELINES
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APPLICATION  GUIDELINES
•
•Soil must be sealed by some means to keep <= /span>MITC gas from escaping too quickly before it = has had time to work.
<= span style=3D'font-size:75%;color:#FF3300'>•Concentration X Duration =3D Fumigation Effect
•
•Plant immediately after satisfying the Labeled waiting period, making sure not to disturb the = treated soil.
•
•
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Drip Irrigation Overview
•Refining Drip Application a major focus with
ØImproved efficacy using 2 lines:
–Use of plastic
–Understanding water movement in soil
–Sequential Drip applications:
•<= /span>Inline followed by K-Pam or Vapam 5-7 days later
•<= /span>Pic EC followed by K-Pam or Vapam 5-7 days later
•<= /span>Other combinations being researched=
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= 0 cm
30 cm
RESULTS